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The Water Wizard

Problem Solving and Pool Water Chemistry 101


The Water Wizard will teach you basic pool water chemistry.  Your pool water should be sparkling, crystal clear and inviting all the time.  The Wizard will give you tips to help achieve that goal.  Learn to recoginize and treat water problems early. 


In a nutshell, keep the water balanced, keep the sanitizer level in the proper range, keep the pool clean, and run the pump all the time.  It is as simple as that.  Now you know the secret to crystal clear, sparkling pool water. 

Water Balance:  There are several factors that create what pool people call balanced water.  Total Alkalinity, Calcium Hardness, Stabilizer, and pH.  When all of these are within the recommended ranges we call the water balanced.  Let's look at them individually.

The pH of your pool water should be within a range of 7.2 to 7.6.  If the pH is lower than 7.2 the pool water is acidic and if left in that condition for long periods of time it can corrode the metal in and around the pool.  It is especially hard on the copper exchanger in you pool heater.  Acidic water will use up the chlorine in the pool, reducing its ability to sanitize.  If the pH gets above 7.6 it can cause cloudy water, scaling around the water line and in the plumbing; chlorine becomes lazy and doesn't do its job as well, and algae grows better in a high pH environment. 

The secret to keeping the pH within the recommended levels is Total Alkalinity which is sodium bicarbinate, which is baking soda.  (Baking Soda from the grocery store is a little expensive for pool use, but if you have a chemical supplier in your area, he probably has it in 50 pound bags for a fraction of what you will pay elsewhere.)  It acts as a buffer for the pH and should be kept between 80 and 120 ppm.  The pH will be low one day so you add a little pH increaser and tomorrow it will be high, so you add a little decreaser, and tomorrow it is low again, etc.  This is what we call pH bounce.  You will never be able to get the pH to stabilize without the Total Alkalinity in the proper range.  Alkalinity is lost through to dilution due to backwashing, vacuuming to waste and refilling the pool.  I recommend testing the alkalinity at least once a month.

Swimming pool water requires 180 to 220 ppm Calcium Hardness, which is Calcium Chloride and can also be purchased at a chemical supply store.  If your calcium level gets low the water becomes aggressive and will pull calcium wherever it can find it.  If you pool is concrete or gunnite this process can cause premature deterioration.  If you think you don't need it because you have a liner pool, think again.  Everytime you get out of the pool you bring a gallon or so of water out with you and it sits there on your concrete deck, looking for calcium.  Calcium, like alkalinity is lost through dilution.  If you use chlorine as a sanitizer then you probably shock with Calcium Hypochlorite.  Notice the first word there - calcium.  This will help keep your calcium level up.  I recommend testing and replinishing at least once a month.

Sanitizers:  The most common pool sanitizer is chlorine, usually in the form of tablets or sticks.  If you sanitize your pool with chlorine, you should use a form of chlorine that has Stabilizer in it.  This is cyanuric acid which is combined with the chlorine during the manufacturing process.  Stabilizer acts as a sunscreen for the chlorine.  The sun can remove up to 5 ppm of chlorine from your pool water in 4 hours.  That makes it difficult to keep a chlorine level of 1 to 3 ppm in pool water without stabilizer.  You will need to add stabilizer to a fresh filled pool to bring the level up to between 30 and 50 ppm.  The chlorine tablets you use to sanitize the pool will usually replenish what you loose to dilution during the season. but check it every year when you open the pool.  If you have a salt chlorine generator, you will need to add stabilizer to the water to protect the unstabilized chlorine manufactured by the system. 

Biguinide is a non-chlorine sanitizer.  It is liquid and the biguinide level should be kept between 30 and 50 ppm.  Biguinides are not affected by sunlight and you will not need stabilizer.

Water Testing:  Test the water balancing chemicals at least once a month and test you sanitizer at least weekly.  Use test strips or the drops.  You have a pretty wide range on the balancing chemicals and either is accurate enough to keep you within the range.  You might want to have the water tested at a pool store occasionally, just to see how well you are doing. 

Run that Pump: You may be saving money on the electric bill by only running the pump 8 to 12 hours per day.  Unfortunately, all of that savings will go into chemicals to deal with your water problems.  The pump pulls water out of the pool and forces it into the filter where it is cleaned and then sent through the chlorinator where sanitizer is added and it returns to the pool.  When the pump is off the water isn't being filtered, and sanitizer isn't being added to replace what is being used by dust, leaves and other debris falling out of the air.  In addition to that, the water is just sitting.  Poor water circulation is the primary cause of pool water problems

Water Circulation:  If your pool has a main drain, keep it open.  It pulls water from the bottom of the pool through the filter and it helps keep the water moving.  If you don't have a main drain, point the water return inlet at the deep end toward the bottom of the pool so it will move that water.  Othewise point them slightly down and in the same direction so the water moves around the pool.  It is worth repeating again.  Poor water circulation is the primary cause of pool water problems. 

Cloudy Water:  Poor circulation and filtration are the most common cause of cloudy water. Water appears cloudy because tiny, microscopic particles are suspended in it. It is the filter's job to take these out, but when the pump is off, the water isn't moving through the filter. At the first sign of cloudy water, increase the pump running time.  Shock will burn out these particles. Follow the manufacturer's directions. You may also want to add a blue clarifier to the pool water to aid your filter in catching these particles.  A high pH can cause cloudy water so test the water.  If you are going to have to  treat the pool for algae, your chemicals will be more effective if the water is balanced.  The early stages of an algae bloom can also cause cloudy water.  Feel of the walls and if they are slick, treat the pool for green algae, fast. 

Green Algae:  First determine that what you have really is green algae.  Mustard algae will eventually turn your water green too.  Green algae will usually cause your water to look cloudy a day or two before it turns green.  Green algae will grow on the pool surfaces and cause them to feel slick.  Make sure the water is balanced and the pH is in the 7.2 to 7.6 range (a little closer to the low side is better).  Double shock the pool.  That would be 1 pound of shock for every 5,000 gallons of water, or if you use biguinide, 1 gallon of shock per 5,000 gallons of water.  Run the pump continuously until the water clears.  Frequently the algae will die and the chlorine bleaches it out and the water looks milky.  A blue clarifier added to the water will help the filter clear this out.  There are products on the market which will help your filter remove the phosphates from the water. If you can keep the phosphate level near zero, algae can't grow in your water.  I know people in the pool industry who don't like to sell this product because when pools don't get algae, their algaecide chemical sales go down.  That means you are saving money! 

Mustard Algae:  Mustard algae is more common in pools with poor circulation.  It usually first appears around the corners and on the steps.  It looks like sand and it scatters like dust when you brush it.  You can vacuum it out and it will be back tomorrow.  First, vacuum the pool with the multiport valve set to waste or drain.  It is so fine it will usually come right back through the filter if you vacuum on filter.  There are two ways to treat it in pools sanitized with chlorine.  You can use a copper algaecide.  Follow the manufacturer's directions.  You will want to follow up with a metal chelating agent after the algae is dead.  This will keep the copper from leaving stains on the pool's surfaces.  You can also use a sodium bromide product along with shock, again following the manufacturer's directions.  This is my choice of treatments.  Most of the products that chelate the metals in pool water contain phosphoric acid and add phosphates to the water, and phosphates are algae food.  This is why I see people treat mustard algae and it is back in a couple of weeks.  Use one of the products on the market which will help your filter to remove phosphates.  If you can keep the phosphate level near zero, algae can't grow in your water. 

Keep the pool clean.  Empty the baskets regularly, especially during times when the leaves are falling in the water.  A full basket will slow the circulation through your filter and poor circulation is what?  Right, the primary cause of pool water problems.  Use your automatic pool cleaner and if it has a bag, empty it often, or manually vacuum the pool.  Leaves and other debris that get into your pool water use up the sanitizer.  Sanitizer has two jobs, keeping the pool sanitary, and preventing algae growth. 

The Water Wizard will be adding tips to this site from time to time, so check back.